ISSN:1003-8620

CN:42-1243/TF

主管:中信泰富特钢集团股份有限公司

主办:大冶特殊钢有限公司

特殊钢 ›› 2022, Vol. 43 ›› Issue (1): 53-56.

• 工艺技术 • 上一篇    下一篇

高耐候结构用 Q355GNH 钢的开发与性能研究

孙 傲, 刘志伟, 张瑞琦, 郭晓宏, 吴成举, 高洪涛, 孙 杭   

  1. 鞍钢集团钢铁研究院,鞍山 114009
  • 收稿日期:2021-04-12 出版日期:2022-01-25 发布日期:2022-03-18
  • 作者简介:孙 傲(1990-),男,硕士(2017 年辽宁科技大学),工程师,2014 年辽宁科技大学(本科) 毕业,耐候钢研发。

The Development and Properties study of High Weathering Structural Steels Q355GNH

Sun Ao, Liu Zhiwei, Zhang Ruiqi, Guo Xiaohong, Wu Chengju, Gao Hongtao,Sun Hang   

  1. Ansteel Group Iron and Steel Research Institute, Anshan 114009
  • Received:2021-04-12 Published:2022-01-25 Online:2022-03-18

摘要: 通过对高耐候钢产品的性能要求分析,本试验钢在成分设计上以Cu、P为基,添加少量Cr、Ni,并制定相应的轧制及卷取工艺而成功开发了355强度级别的高耐候结构用钢。对该试验钢的各项性能进行检测,同时根据其成分设计进行了耐腐蚀性能预测,并利用实验室加速腐蚀试验方法对Q355GNH试验钢及Q345B对比钢的腐蚀速率以及其锈层构成进行了评估与观察。结果表明:试验钢的各力学性能指标及低温(-40℃)冲击韧性均远满足国标要求;经成分预测分析,试验钢的耐大气腐蚀性指数为7.13,远超标准要求;且在相同腐蚀条件下,Q355GNH试验钢平均相对腐蚀速率仅为对比Q345B钢的47.40%;与Q345B钢相比,Q355GNH试验钢在周浸腐蚀后表面生成一种呈絮状团簇、致密的锈层。经观察,该锈层中具有保护作用的稳定相α-FeOOH含量相对较高(α-FeOOH:18.2%、Fe3O4:9.1%),使得该锈层结构对基体起到了保护作用。

关键词: 含P高耐候钢, 力学性能, 腐蚀性能, 锈层

Abstract: Through the analysis of the performance requirements of high weathering steels, the composition design of test steel is based on Cu and P, with the addition of a small amount of Cr and Ni. Combined with the corresponding rolling and coiling process, and a 355 strength grade high weathering steels was successfully developed. The mechanical properties of test steels were tested, and the corrosion resistance was predicted according to its composition design. The corrosion rate and rust layer composition of Q355GNH test steels and Q345B steels were evaluated and observed by the method of laboratory accelerated corrosion test. The results show that the various mechanical properties and low temperature (-40℃) impact toughness of test steels far meet the requirements of national standard; The atmospheric corrosion resistance index of test steels is 7. 13, far exceeding the standard requirements. The average relative corrosion rate of Q355GNH test steel is only 47.40% of the comparative Q345B steel under the same corrosion conditions. Compared with Q345B steel, a flocculent, dense rust layer is formed on the surface of Q355GNH test steel after alternate immersion test, and it is observed that the content of stable phase α-FeOOH with protective effect is relatively high in the rust laye(α-FeOOH : 18. 2%、Fe3O4 : 9. 1% ), which makes the structure of the rust layer play a protective role on the matrix.