ISSN:1003-8620

CN:42-1243/TF

主管:中信泰富特钢集团股份有限公司

主办:大冶特殊钢有限公司

特殊钢

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LF精炼工艺对36MnVNS4含硫非调质钢硫含量和夹杂物形貌的影响

熊玉影,张贤忠   

  1. (宝钢股份中央研究院武汉分院,武汉430080)
  • 出版日期:2022-02-26 发布日期:2022-02-26

Effect of LF Refining Process on Sulphur Content and Morphology of Inclusions in Sulphur Bearing Non-Quenching and Tempering Steel 36MnVNS4

Xiong Yuzhang,Zhang Xianzhong   

  1. (Wuhan Branch, Baosteel Central Research Institute, Wuhan 430080)
  • Published:2022-02-26 Online:2022-02-26

摘要: 试验的 36MnVNS4 含硫非调质钢(/% :0. 36C, 0. 66Si, 1. 00Mn,0. 010P, 0. 045S,0. 26V, 0.0110N)的冶炼工艺流程为铁水+废钢-70 t EBT EAF-LF-方坯连铸-轧制。研究了 LF 19. 82% A12O3, (CaO)/( SiO2) =2.64和14. 63% A12O3,(CaO)/(SiO2) =2.15两种渣系精炼对软吹后钢中氧含量,喂S线后S的收得率以及钢中夹杂物成 分和形貌的影响。结果表明,高碱度白渣精炼工艺有利于钢中氧含量的降低,但不利于钢中硫含量的稳定;精炼渣碱度(CaO)/(SiO2 )由2. 64降低至2. 15时,有利于钢中硫含量的稳定控制,硫的回收率由35%提高至75%;两种精炼工艺下钢中的夹杂物分布、形貌和组成基本相同。通过钢包钙处理,长条状MnS夹杂转变为球状复合夹杂。

关键词: 含硫非调质钢, LF精炼, 精炼渣碱度, 脱氧, 钙处理, 硫化物

Abstract: The steelmaking process flowsheet of tested sulphur bearing non-quenching and tempering steel 36MnVNS4 (/% : 0.36C, 0.66Si, l.00Mn, 0.010P, 0.045S, 0.26V, 0.0110N) is hot metal + scrap- 70 t EBT EAF-LF-square billet casting-rolling. The effect of LF both slag series- 19. 82% A12O3, ( CaO)/( SiO2 ) = 2. 64 and 14. 63% A12O3, (CaO)/(SiO2) =2. 15 on oxygen content in liquid after soft argon blowing, S yield after feeding S wire, and compound and morphology of inclusions in steel has been studied. Results show that refining by high basicity white slag is available to decrease the oxygen content in steel, but it is unfavourable to stabilize the sulphur content in steel;decreasing the refining slag basicity (CaO)/( SiO2) from 2. 64 to 2. 15 is favourable to stabilized control the sulphur content in steel, and the yield of sulphur increases from 35% to 75% ; with both refining process the distribution, morphology and ingredient of inclusions in steel are basically the same. By calcium treatment in ladle the long strip MnS inclusions modify to spheroid compound inclusions.

Key words: Sulphur Bearing Non-Quenching and Tempering Steel, LF Refining, Basicity of Refining Slag, Deoxidation, Calcium Treatment, Sulphide