万勇, 陈伟庆, 吴绍杰. Effect of Calcium and Boron on Structure and Magnetic Properties of Non-Oriented Silicon Steel[J]. Special Steel, 2013, 34(5): 64-67.DOI:
The 3 kinds of non-oriented silicon steel (/% : 0.004-0.006C
1.31-1.38Si
0.34-0.41Mn
0.004S
0.027P
0.36-0.41Als
0.0022-0.0028 T[O
]
0.0048-0.0060N) - non containing Ca and B
containing Ca (0.0026% Ca)
and containing Ca-B (0.0027% Ca and 0.0045% B) is melted by a 6.5 kg vacuum induction furnace
forged to 70 mm flat blank
hot-rolled to 2.5 mm plate
normalized at 950 °C and cold-rolled to 0.5 mm sheet then in 30% H
2
+ 70% N
2
atmosphere annealed at 920 for 3 min
furnace cooling. Test results show that with adding calcium treatment the CaO • 6A1
2
O
3
and
CaS form in the non-oriented silicon steel it is available to inhibit the deposition of MnS precipitate and favourable to promote the grain growth ; in annealed cold-rolled sheet of non-oriented silicon steel containing Ca and B
the BN has not been found; the annealed cold-rolled sheet of steel containing 0.0026%Ca has strongest
{100}
face texture and Goss texture; while that of steel containing 0.0027% Ca and 0.0045% B has weakest {112}
<
110>texture. In three heats of test steels
the comprehensive magnetic property of the steel containing 0.002 6% Ca is best i. e. its iron loss P