杨吉春, 余海存, 石磊. Effect of RE Element Ce on Behavior of Corrosion Resistance of A36 Steel Plate for Shipbuilding[J]. Special Steel, 2014, 35(2): 43-46.DOI:
Test normal A36 steel and containing Ce A36Ce steel for shipbuilding (/% : 0.12-0.13C
0.21 Si
0.77-0.79Mn
0.013-0.015P
0.003-0.004S
0.32-0.33Cr
0.023-0.025Al
0-0.009Ce) are melted by vacuum induction furnace
cast to 7 kg ingot
forged to 25 mm x 25 mm billet and normalized at 865 °C for 0. 5 h. The corrosion rate
corrosion surface morphology and features of rust layer of both normal non-containing Ce A36 steel plate for shipbuilding and containing 0.009% Ce A36Ce plate for shipbuilding are analyzed by full immersion examination in simulated seawater (3. 5% NaCI) environment with using weight loss
electrochemical method
scanning electron microscope and X- ray diffractometry. Results show that in seawater for 30 day
the corrosion rate of A36 steel plate for shipbuilding is 1.8 g/ (mm
2
• day)
while that of A36Ce steel plate for shipbuilding is 1.2 g/( mm
2
• day) ; the A36Ce steel plate is easily to form denser black inner rust layer which is not easily to peel off ; the pitting corrosion tendency of nonnal A36 steel plate is more severe
but the uniform corrosion of A36Ce steel plate is primary ; the corrosion products of both steels are iron oxide and carbonyl.