方忠强, 孙彦辉, 汪成义, 等. 120 t BOF-LF-RH-CC流程冶炼石油套管钢时TiN的析出和控制[J]. 特殊钢, 2014,35(5):30-33.
方忠强, 孙彦辉, 汪成义, et al. Precipitation and Control of Titanium Nitride in Oil Casing Tube Steel Steelmaking by 120 t BOF-LF-RH-CC Flow Sheet[J]. Special Steel, 2014, 35(5): 30-33.
方忠强, 孙彦辉, 汪成义, 等. 120 t BOF-LF-RH-CC流程冶炼石油套管钢时TiN的析出和控制[J]. 特殊钢, 2014,35(5):30-33.DOI:
方忠强, 孙彦辉, 汪成义, et al. Precipitation and Control of Titanium Nitride in Oil Casing Tube Steel Steelmaking by 120 t BOF-LF-RH-CC Flow Sheet[J]. Special Steel, 2014, 35(5): 30-33.DOI:
石油套管用钢(/%:0.26~0.29C,0.25~0.35Si,0.40~0.50Mn,≤0.009P,≤0.004S,0.95~1.05Cr,0.09~0.11V,0.02~0.04Al,0.015~0.020Ti,≤0.0060N)的生产流程为铁水预处理-120 t BOF-吹氩-LF-喂CaSi线-RH-合金化-喂CaSi线-软吹氩-Φ220 mm圆坯连铸工艺。通过热力学分析得出钢中N含量超过50×10
-6
以及工业试验得出生产的圆铸坯中的N含量为67×10
-6
时
在铸坯中易形成2μm以上的TiN夹杂。通过控制BOF终点[N
]
≤30×10
-6
LF终点[S
]
≤25×10
-6
[O
]
≤25×10
-6
[N
]
≤35×10
-6
RH合金化后终点[N
]
≤35×10
-6
[H
]
≤1.5×10
-6
稳定喂CaSi线速度300~400 m/min
控制中间包[N
]
≤40×10
-6
严格连铸保护浇铸工艺
则铸坯中的N含量≤50×10
-6
钢中TiN夹杂数量显著下降
未发现大尺寸TiN夹杂物。
Abstract
The production flow sheet for oil casing tube steel (/% : 0.26-0.29C
0.25-0.35Si
0.40-0.50Mn
≤0.009P
≤0.004S
0.95-1.05Cr
0.09-0.11V
0.02-0.04Al
0.015-0.020Ti
≤0.0060N) is hot metal pretreatment-120 t BOF-argon blowing-LF-CaSi wire feeding-RH-Alloying-CaSi wire feeding-soft argon blowing-Φ200 mm round bloom casting process. By commercial test as the N content in produced round casting bloom is 67 x 10
-6
and by thermodynamic analysis as the N content in steel is more than 50 x 10
-6
the more than 2 μm TiN inclusions easily form in casting bloom. With controllin
g BOF end [N
]
≤ 30 X 10
-6
LF end [S
]
≤ 25 X 10
-6
[O
]
≤ 25 X 10
-6
and [N
]
≤ 35 X 10
-6
after alloying RH end [N
]
≤ 35 x 10
-6
and [H
]
≤ 1.5 x 10
-6
stably feeding CaSi wire speed 300-400 m/min and controlling tundish [N
]
≤ 40 x 10
-6
and strict casting-shielding process
the N content in casting bloom shall be ≤ 50 X 10
-6
the amount of TiN inclusions in steel decreases markedly and there are not larger size TiN inclusions to be found in steel.