1. 北京科技大学冶金与生态工程学院,北京,100081
2. 钢铁研究总院连铸技术国家工程研究中心,北京,100083
3. 河北钢铁股份有限公司承德分公司,承德,067002
[ "张明博(1984-),男,博士研究生(钢铁研究总院、北京科技大学),2007年河北理工大学(专科)毕业,品种钢开发与冶 炼研究。" ]
收稿:2015-12-13,
网络首发:2022-08-02,
纸质出版:2016-08-02
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张明博, 仇圣桃, 朱荣, 等. 转炉CaO渣系加锂云母矿冶炼超低磷钢的热力学分析和工业试验[J]. 特殊钢, 2016,37(3):13-19.
张明博, 仇圣桃, 朱荣, et al. Analysis on Thermodynamics of BOF Smelting Ultra-Low Phosphorous Steel by CaO Series Slag Adding Lepidolite and Commercial Test[J]. Special Steel, 2016, 37(3): 13-19.
通过共存理论计算和热力学分析得出添加锂云母矿形成的CaO-MgO-FeO-Li
2
O-Na
2
O-K
2
O-SiO
2
-P
2
O
5
复合脱磷渣的渣-钢磷分配比Lp明显高于CaO-MgO-FeO-SiO
2
-P
2
O
5
基本渣系
并确定锂云母矿的加入最佳时期是转炉吹炼前期。10炉120 t转炉冶炼的超低磷钢的结果表明
与未加锂云母矿的炉次相比
加锂云母矿可以使半钢[P
]
快速降低至0.044%以下
并且半钢脱磷率和磷分配比Lp分别从40.62%和13.13提高到67.71%和36.89
使转炉平均终点脱磷率和磷分配比Lp分别从92.35%和130.7提高到94.85%和191.9
转炉终点[P
]
可以控制在0.005%~0.007%
[P
]
的命中率100%
此复合渣系满足超低磷钢生产要求。
It is obtained by coexistence theory calculation and thermodynamics analysis that the slag-steel phosphorus partition ratio Lp of compound dephosphorizing slag CaO-MgO-FeO-Li
2
O-Na
2
O-K2O-SiO
2
-P
2
O
5
is obviously higher than that of basic dephosphorizing slag series CaO-MgO-FeO-SiO
2
-P
2
O
5
and defined that the optimum adding lepidolite period is the early stage of BOF blowing. The results of 10 heats 120 t BOF smelting ultra-low phosphorus steel show that as compared with the heats non-adding lepidolite
the semisteel [P
]
of heats by adding lepidolite decreases quickly to less than 0. 044%
the semi-steel dephosph
orization ratio and phosphorus partition ratio Lp respectively increase from 40. 62% and 13.13 to 67.71% and 36. 89
and the BOF average end dephosphorization ratio and phosphorus partition increase respectively from 92.35% and 130.7 to 94. 85% and 191.9
and the BOF end [P
]
can be controlled in 0.005% ~0. 007% with [P
]
percentage of hits 100%
so the compound slag series meet the requirement of ultra-low phosphorus steel production.
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