1. 钢铁研究总院冶金工艺研究所,北京,100081
2. 山西太钢不锈钢股份有限公司技术中心,太原,030003
收稿:2016-08-28,
网络首发:2022-07-28,
纸质出版:2017-07-28
移动端阅览
翟俊, 郎炜旳. 304奥氏体不锈钢180 t AOD-LF精炼过程夹杂物衍变行为的研究[J]. 特殊钢, 2017,38(1):9-12.
翟俊, 郎炜旳. A Study on Evolution Behavior of Inclusions in Austenite Stainless Steel 304 during 180 t AOD-LF Refining Process[J]. Special Steel, 2017, 38(1): 9-12.
采用氧氮分析仪、扫描电镜、金相显微镜研究了160 t EAF-180 t AOD-LF-CC工艺生产304不锈钢的冶炼过程中全氧含量和夹杂物数量、尺寸、成分、类型等的衍变行为。AOD初始[C
]
2.0%3.0%
[Si
]
0.2%~0.4%
终点[C
]
0.04%~0.06%
AOD终渣为(/%):53.9%CaO
30.1SiO
2
1.34Al
2
O
3
5.22MgO
8.74CaF
2
0.39Cr
2
O
3
0.53TFe
0.62MnO
LF终渣为(/%):57.9CaO
21.6SiO
2
1.70Al
2
O
3
6.30MgO
0.03Cr
2
O
3
11.9CaF
2
0.26TFe
0.31 MnO。结果表明
AOD-LF-CC过程中氧含量逐渐降低
脱氧率达到71.0%
铸坯氧含量为25×10
-6
在精炼过程中大型夹杂物数量明显降低
铸坯中没有出现≥20μm的夹杂物;在精炼过程钢中夹杂物主要以低熔点的硅酸盐为主
从LF终点至铸坯夹杂物中MgO和Al
2
O
3
含量分别升高了12%和17.5%
因温度降低
铸坯中残余的Mg、Al和O不断结合析出MgO-Al
2
O
3
尖晶石
同时残余的Mg、Al与低熔点的硅酸盐夹杂物发生反应形成高熔点的硅酸盐
所以铸坯中夹杂物主要以镁铝尖晶石和高熔点硅酸盐为主。
The evolution behavior of total oxygen content and amount
size
ingredient and type of inclusions in steel during steelmaking process of stainless steel 304 by 160 t EAF-180 t AOD-LF-CC flowsheet has been studied by nitrogen oxygen analyzer
optical and scanning electron microscope. The AOD refining process main operation data are initial [C
]
2.0% 〜3.0%
[Si
]
0.2% 〜0.4%
end [C
]
0.04% 〜0.06%
end AOD slag ingredient (/
%): 53.9CaO
30. 1 SiO
2
1. 34Al
2
O
3
5. 22MgO
8. 74CaF
2
0. 39Cr
2
O
3
0. 53TFe
0. 62MnO
and end LF slag ingredient (/%): 57.9CaO
21.6SiO2
1.70Al
2
O
3
6. 30MgO
0. 03Cr
2
O
3
11.9CaF
2
0. 26TFe
0.31MnO. Results show that in AOD- LF-CC process the oxygen content in steel decreases gradually
the deoxidized ratio is up to 71. 0% and the oxygen content in casting slab is 25 x 10
-6
the amount of large inclusions decreases obviously in refining process
and there is no ≥20μm inclusion occurring in casting bloom ; during refining process the main inclusions in steel are low-melting silicate
and from end LF to cast slab the MgO and Al
2
O
3
content in inclusions increase respectively by 12% and 17. 5%
due to temperature decreasing
in cast slab the residual Mg
Al continuously combined with 0 to precipitate MgO-Al
2
O
3
Aspinel and residual Mg and Al reacting with low-melting siHcate to form high-melting silicate
therefore the inclusions in cast slab are mainly magnesium-aluminium spinel and high-melting silicate.
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