1.海洋装备用金属材料及其应用国家重点实验室,鞍山 114009
2.鞍钢集团钢铁研究院,鞍山 114009
3.青岛市旅游规划建筑设计研究院有限公司,青岛 266000
赵波(1981—),女,硕士,高级工程师; E-mail:zhaobo198105@126.com
收稿:2024-01-19,
纸质出版:2024-11-30
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赵波,王善宝,解德刚等.无缝钢管Gr.6轧制及正火后的组织和性能分析[J].特殊钢,2024,45(06):102-107.
Zhao Bo,Wang Shanbao,Xie Degang,et al.Microstructure and Properties of Seamless Steel Pipe Gr.6 after Rolling and Normalizing[J].Special Steel,2024,45(06):102-107.
赵波,王善宝,解德刚等.无缝钢管Gr.6轧制及正火后的组织和性能分析[J].特殊钢,2024,45(06):102-107. DOI: 10.20057/j.1003-8620.2024-00018.
Zhao Bo,Wang Shanbao,Xie Degang,et al.Microstructure and Properties of Seamless Steel Pipe Gr.6 after Rolling and Normalizing[J].Special Steel,2024,45(06):102-107. DOI: 10.20057/j.1003-8620.2024-00018.
利用光学显微镜、扫描电镜、透射电镜分析及力学试验、腐蚀试验等,分析了热轧态和正火态Gr.6钢管组织形貌、低温性能及耐腐蚀性能。结果表明,研制的低温无缝钢管Gr.6热轧态及正火态低温力学性能及抗腐蚀性能满足标准要求,热轧态显微组织为珠光体+铁素体,晶粒均匀细小,但带状组织明显。析出相以TiN颗粒为主,在-60 ℃发生韧脆转变,经过900 ℃正火热处理后,晶粒更为细小,晶粒度达到10级以上,正火态试样大角度晶界差比例高于热轧态,大角度界面密度也有所增加。析出相主要为TiN+少量的VN颗粒,且在-80 ℃仍未发生韧脆转变。通过快、慢极化扫描速率的极化试验研究了材料的腐蚀行为。腐蚀试验表明,正火态试样在电化学模拟溶液中应力腐蚀敏感性较小,而热轧态试样的应力腐蚀敏感性较大。因此,正火态相比热轧态电化学腐蚀性能更优,适合更加苛刻的腐蚀环境。
The microstructure morphology, low-temperature performance, and corrosion resistance of hot-rolled and normalized condition Gr.6 steel pipes were analyzed using optical microscopy, scanning electron microscopy, transmission electron microscopy, mechanical testing, and corrosion testing. The results show that the low-temperature mechanical properties and corrosion resistance of the developed low-temperature seamless steel pipe Gr.6 in the hot-rolled and normalized states meet the standard requirements. The microstructure in the hot-rolled state is pearlite and ferrite, with uniform and fine grains, but the banded structure is obvious.The precipitated phase is mainly composed of TiN particles, which undergo a ductile brittle transition at -60 ℃. After 900 ℃ normalizing heat treatment, the grains become finer, with a grain size of 10 grade or above. The proportion of large angle grain boundary differences in the normalized state sample is higher than that in the hot-rolled state, and the density of the large angle interface also increases. The precipitate phase is mainly TiN and a small amount of VN particles, and no ductile brittle transition has occurred at -80 ℃.The corrosion behavior of the material was studied through polarization tests with fast and slow polarization scanning rates. Corrosion tests have shown that the stress corrosion sensitivity of normalized specimens is relatively low in electrochemical simulation solutions, while the stress corrosion sensitivity of hot-rolled specimens is relatively high. Therefore, the electrochemical corrosion performance of the normalized state is better than that of the hot-rolled state, and it is suitable for more harsh corrosion environments.
张银桥 , 黎福华 , 孔繁革 , 等 . -70 ℃低温用09MnNiD钢Φ219 mm×20 mm无缝管生产实践 [J]. 特殊钢 , 2022 , 43 ( 4 ): 66 - 69 .
吴小林 , 张 明 , 孙宪进 , 等 . 抗H 2 S腐蚀钢板的失效机理研究 [J]. 特殊钢 , 2019 , 40 ( 4 ): 12 - 15 .
孙 毅 , 贾改风 , 李冠楠 , 等 . 海底用耐腐蚀管线钢X60MOS的开发 [J]. 轧钢 , 2021 , 38 ( 3 ): 27 - 31 .
Hejazi D , Haq A J , Yazdipour N , et al . Effect of manganese content and microstructure on the susceptibility of X70 pipeline steel to hydrogen cracking [J]. Materials Science and Engineering: A , 2012 , 551 : 40 - 49 .
Xue H B , Cheng Y F . Characterization of inclusions of X80 pipeline steel and its correlation with hydrogen-induced cracking [J]. Corrosion Science , 2011 , 53 ( 4 ): 1201 - 1208 .
陈 燕 , 张哲平 , 张传友 , 等 . 含Nb管线钢针状铁素体相变动力学研究 [J]. 钢管 , 2020 , 49 ( 2 ): 14 - 18 .
熊 刚 , 夏文斌 , 李端正 , 等 . X65QO Φ457 mm×25.4 mm大口径深海海底无缝钢管的开发和应用 [J]. 特殊钢 , 2021 , 42 ( 5 ): 41 - 45 .
程 石 , 胡 锋 , 王亚超 , 等 . 回火热处理对低碳高强度钢低温冲击韧性的影响 [J]. 材料热处理学报 , 2020 , 41 ( 12 ): 80 - 89 .
吴世杰 , 刘丽霞 , 彭 军 . 珠光体片层间距对U71Mn重轨钢初期腐蚀的影响 [J]. 材料热处理学报 , 2020 , 41 ( 11 ): 87 - 93 .
徐永康 , 刘耀恒 . 微合金化在正火态管线用无缝钢管中的应用 [J]. 钢管 , 2015 , 44 ( 4 ): 11 - 15 .
Parkins R N . Predictive approaches to stress corrosion cracking failure [J]. Corrosion Science , 1980 , 20 ( 2 ): 147 - 166 .
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