江阴兴澄特种钢铁有限公司,江阴 214429
张永启(1989—),男,硕士,工程师; E-mail:x8102271818@citicsteel.com
收稿:2025-05-08,
纸质出版:2026-05-30
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张永启,高海丰,高坤等.精炼底吹氮气稳定控制齿轮钢氮含量的研究与实践[J].特殊钢,2026,47(03):54-58.
Zhang Yongqi,Gao Haifeng,Gao Kun,et al.Research and Practice on Stable Control of Nitrogen Content in Gear Steel by Bottom Blowing Nitrogen During Refining Process[J].Special Steel,2026,47(03):54-58.
张永启,高海丰,高坤等.精炼底吹氮气稳定控制齿轮钢氮含量的研究与实践[J].特殊钢,2026,47(03):54-58. DOI: 10.20057/j.1003-8620.2025-00130.
Zhang Yongqi,Gao Haifeng,Gao Kun,et al.Research and Practice on Stable Control of Nitrogen Content in Gear Steel by Bottom Blowing Nitrogen During Refining Process[J].Special Steel,2026,47(03):54-58. DOI: 10.20057/j.1003-8620.2025-00130.
研究了精炼过程(LF、VD)底吹氮气替代含氮合金芯线对齿轮钢进行氮合金化的工艺,重点解决了稳定控制钢液氮含量的核心难题。通过热力学和动力学分析,明确了钢液成分(特别是S、O含量)、氮分压、吹氮流量和时间等关键因素的影响机制。通过以下措施实现稳定控制氮含量的:严格控制LF进站钢液
w
[S]≤0.025%,以降低界面阻力,提高增氮效率;在LF精炼阶段,采用优化的氮气分压0.4~0.7 MPa和流量0.9 m³/(min·t),结合吹氮时间控制初始增氮量;在VD真空处理阶段,灵活采用底吹氮气工艺(分压0.7 MPa,流量0.6 m³/(min·t)),利用增氮与脱氮的动态平衡实现氮含量的微调与稳定。生产实践结果表明,通过上述综合控制手段,LF精炼和VD真空处理以氮气作为搅拌气体可有效进行合金化操作,能够将齿轮钢20MnCrS5的最终氮含量稳定控制在(100~140 )×10
-6
的目标范围内。研究还发现,钢液中S含量是影响LF吹氮增氮效果的关键因素,S含量越低(
w
[S]≤0.025%),增氮速率越高(约6.9×10
-6
min
-1
)。VD真空精炼使用氮气替代氩气会存在钢液增氮和脱氮的共存现象,表现出的是增氮现象,增氮速率约2.19×10
-6
min
-1
。
This paper investigates the process of nitrogen alloying in gear steel by bottom blowing nitrogen during refining process (LF and VD) as a substitute for nitrogen-containing alloy cored wires, focusing on solving the core challenge of stably controlling the nitrogen content in molten steel. Through thermodynamic and kinetic analysis, the influence mechanisms of key factors such as molten steel composition (especially S and O content), nitrogen partial pressure, nitrogen blowing flow rate and time were elucidated. To achieve stable control of nitrogen content through the following measures:Strictly control the sulfur
w
[S] content of the molten steel entering the LF station to ≤ 0.025%, reducing interfacial resistance and enhancing nitrogen pickup efficiency; During the LF refining stage, employ optimized nitrogen partial pressure (0.4 MPa-0.7 MPa) and flow rate 0.9 m³/(min·t), combined with controlled nitrogen blowing time to manage the initial nitrogen increase.In the VD vacuum treatment stage, the bottom blowing nitrogen process (partial pre
ssure 0.7 MPa, flow 0.6 m³/(min·t)) is flexibly adopted to achieve the fine adjustment and stability of nitrogen content by using the dynamic balance between nitrogen increase and nitrogen removal.Production practice results demonstrate that through the above comprehensive control means, utilizing nitrogen as the stirring gas in both LF refining and VD vacuum treatment enables effective alloying operation, and the final nitrogen content of gear steel grade 20MnCrS5 can be stably controlled within the target range of (100-140)×10
-6
. The study also find that the S content in molten steel is the key factor affecting the effect of nitrogen increase by blowing nitrogen in LF, and the lower the S content (
w
[S]≤0.025%), the higher the nitrogen increase rate (approximately 6.9×10
-6
min
-1
).In VD vacuum refining process, nitrogen is used instead of argon, and the coexistence phenomenon of nitrogen increase and nitrogen removal in molten steel exists, which shows the phenomenon of nitrogen increase with an approximate rate of 2.19×10
-6
min
-1
.
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