ISSN:1003-8620

CN:42-1243/TF

主管:中信泰富特钢集团股份有限公司

主办:大冶特殊钢有限公司

特殊钢 ›› 2015, Vol. 36 ›› Issue (5): 27-31.

• 工艺技术 • 上一篇    下一篇

碱金属氧化物对转炉冶炼超低磷钢脱磷效果影响的工业试验

秦哲1,张明博1,2,廖建军3,廖鹏3,仇圣桃1   

  1. 1. 钢铁研究总院连铸技术国家工程研究中心,北京 100081 ;
    2. 河北钢铁集团承钢公司,承德 076001;
    3. 新余钢铁股份有限公司第二炼钢厂,新余 338001;
  • 出版日期:2015-10-01 发布日期:2022-08-15
  • 作者简介:秦哲(1977-),男,博士,高级工程师,2001年鞍山钢铁学院(本科)毕业,精炼工艺与钢水洁净度控制。

Commercial Pilot Production of Effect of Alkali Metal Oxides on Dephosphorization Results of Converter Smelting Ultra-Low Phosphorous Steel

Qin Zhe1 , Zhang Mingbo1,2 , Liao Jianjun3 , Liao Peng3 , Qiu Shengtao1   

  1. 1. National Engineering and Research Center of Continuous Technology Center, Central Iron and Steel Research Institute,Beijing 100081 ;
    2. Chengde Iron, and Steel Company, Hebei Iron and Steel Co Ltd, Chengde 076001 ;
    3. Second Steelmaking Plant, Xinyu Iron and Steel Co Ltd, Xinyu 338001;
  • Published:2015-10-01 Online:2022-08-15

摘要: 通过15 kg真空感应炉试验得出CaO基脱磷渣系中分别添加Li2O、CaF2、Na2O、K2O后均有明显的脱磷效果,其中Li2O含量5%~10%时脱磷效果最佳。120 t顶底复吹转炉双渣操作的工业试验结果表明,脱磷前期在加31.46 kg/t石灰、3.70 kg/t白云石和0.70 kg/t烧结矿的基础上添加13.88 kg/t锂云母矿(/%:56.41SiO2,3.80FeO,4.50Na2O,4.17K2O,3.18Li2O)较未加锂云母矿的渣料(34.58 kg/t石灰,5.41 kg/t白云石,3.13 kg/t的烧结矿)转炉终点渣氧化性低,转炉半钢的脱磷率和磷平衡分配比的平均值分别是未加锂云母矿的1.67倍和2.81倍,转炉终点的脱磷率和磷平衡分配比的平均值是未加锂云母矿的1.02倍和1.47倍,与未加锂云母矿相比,转炉吹炼终点[P]可由0.009%~0.011%降低到0.005%~0.006%,能够满足超低磷钢生产要求。

关键词: 120 t顶底复吹转炉, 脱磷渣系, 超低磷钢, 碱金属氧化物, 锂云母矿, 脱磷

Abstract: By testing in a 15 kg vacuum induction furnace it is obtained that there is obvious dephosphorization effect by respectively adding Li2O, CaF2, Na2O and K2O in CaO base dephosphorization slag series, of them the CaO base slag containing 5% 10% Li2O has optimum dephosphorization results. The results of commercial pilot production of 120 t top and bottom combined blowing converter with double slag operation show that as compared with the earlier stage slag without adding lepidolite (/% : 34.58 kg/t lime, 5.41 kg/t dolomite and 3.13 kg/t sinter) in earlier stage of dephosphorization based on adding 31.46 kg/t lime, 3.70 kg/t dolomite and 0.70 kg/t sinter, with adding 13.88 kg/t lepidolite mineral (/% : 56.41SiO2, 3.80FeO, 4.50Na2O, 4.17K2O, 3. 18Li2O) the oxidizability of converter end slag is lower, the average dephosphorization rate and phosphorus equilibrium distribution coefficient of converter semi-steel is respectively 1.67 time and 2.81 times that without adding lepidolite, the converter end dephosphorization rate and phosphorus equilibrium distribution coefficient is respectively 1.02 times and 1.47 times that without adding lepidolite, as compared with nonadding lepidolite the converter blowing end [P] decreases from 0.009%-0.011% to 0.005%-0.006% to meet the requirement of ultra-low phosphorus steel.

Key words: 120 t Top and Bottom Combined Blowing Converter, Dephosphorization Slag Series, Ultra-Low Phosphorus Steel, Alkali Metal Oxides, Lepidolite Mineral, Dephosphorization