ISSN:1003-8620

CN:42-1243/TF

主管:中信泰富特钢集团股份有限公司

主办:大冶特殊钢有限公司

特殊钢 ›› 2016, Vol. 37 ›› Issue (1): 43-46.

• 工艺技术 • 上一篇    下一篇

组分对100 t LF高碱度精炼渣粘度和TC80钢脱硫的影响

赵青松1,2, 仇圣桃2, 赖朝彬1, 张明博2, 王晓晶3   

  1. 1江西理工大学冶金与化学工程学院,赣州341000;
    2钢铁研究总院连铸技术国家工程研究中心,北京100081;
    3天津钢铁集团有限公司炼钢二厂,天津300301
  • 收稿日期:2015-08-10 出版日期:2016-02-01 发布日期:2022-08-25
  • 作者简介:赵青松(1987-),男,硕士生(江西理工大学),助理工程师,2011年江西理工大学(本科)毕业,二次精炼工艺研究。

Effect of Ingredient on Viscosity of 100 t LF High Basicity Refining Slag and Desulphurization of steel TC80

Zhao Qingsong1,2, Qiu Shengtao2,  Lai Chaobin1 ,  Zhang Mingbo2, Wang Xiaojing3   

  1. 1 School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000;
    2 National Engineering and Research Center of Continuous Casting Technology, Center Iron and Steel Research Institute,Beijing 100081 ;
    3 The Second Steelmaking Plant, Tianjin Iron and Steel Co Ltd, Tianjin 300301
  • Received:2015-08-10 Published:2016-02-01 Online:2022-08-25

摘要: 试验研究了组分对碱度3~5的LF精炼渣(/%:37.5~54.8CaO,9.8~18.2SiO2,20~30Al2O3,4~10MgO,3~10CaF2)粘度的影响。结果表明,CaF2和Al2O3对渣粘度影响较大,碱度和MgO对粘度影响较小。随着CaF2含量的增加,渣粘度先降低后增加;随着Al2O3含量的增加,渣粘度逐渐降低。渣中Al2O3含量为20%,CaF2≥6%或渣中Al2O3含量为25%,CaF2≥3%时,1500℃渣的粘度值低于0.5 Pa.s。试验得出粘度较优组分为4~5R,25%~30%Al2O3,6%~10%MgO,3%~6%CaF2。100 t LF精炼TC80钢生产试验表明优化后精炼渣将钢水中的硫由0.020%脱至0.005%以下,脱硫率从优化前的72%提高至84%,LF精炼终点平均T[O]为14×10-6。 

关键词: LF精炼渣, 粘度, 正交试验, 组分, 脱硫, 脱氧

Abstract: The effect of ingredient of LF refining slag (/% : 37. 5 ~54. 8CaO, 9. 8 ~ 18. 2SiO2 , 20 ~ 30Al2O3,4 ~ 10MgO, 3 ~ 10CaF2) with basicity 3 ~5 on viscosity has been tested and studied. Results show that the effect of CaF2 and A12O3 on viscosity of refining slag is great and the effect of basicity and MgO on viscosity of refining slag is rather minor. With increasing CaF2 the viscosity of refining slag decreases first and then increases, with increasing A12O3 content in slag the viscosity of slag gradually decreases ; with Al20content in slag being 20% and CaF2 ≥ 6% or A12O3 content being 25% and CaF2 ≥ 3% , the viscosity value of slag at 1 500 °C is less than 0. 5 Pa • s; and it is obtained by test that better basicity R and ingredient of refining slag for viscosity is 4 ~ 5R, 25% ~30% Al2O3,6% 〜10% MgO, 3% 〜6% CaF2. The results of production pilot of 100 t LF refining steel TC80 show that after refining slag optimization the sulfur content in liquid decreases to less than 0. 005% from initial 0. 020% , the desulphurization ratio increases to 84% from before optimization 72% ; and the average T [O] at end refining is 14 x 10-6.

Key words:  , LF Refining Slag, Viscosity, Orthogonal Experiment, Ingredient, Desulfurization, Deoxidation