ISSN:1003-8620

CN:42-1243/TF

主管:中信泰富特钢集团股份有限公司

主办:大冶特殊钢有限公司

特殊钢 ›› 2016, Vol. 37 ›› Issue (2): 16-18.

• 试验研究 • 上一篇    下一篇

石灰微观结构对铁水预处理脱硫的影响

郝华强1,任倩倩1,3,张玉柱1,2,郝素菊2,蒋武锋2,张卫攀2   

  1. 1. 东北大学材料与冶金学院,沈阳 110004;
    2. 华北理工大学冶金与能源学院,现代冶金技术教育部重点实验室,唐山 063009;
    3. 钢铁研究总院先进钢铁流程及材料国家重点实验室,北京 100081;
  • 收稿日期:2015-11-03 出版日期:2016-04-01 发布日期:2022-08-06
  • 通讯作者: 张玉柱
  • 作者简介:郝华强(1977-),男,博士,2001年华北理工大学(本科)毕业,炼钢工艺研究
  • 基金资助:
    国家自然科学基金项目(51174075)
    河北省自然科学基金项目(E2012209024)

Effect of Microscopic Structure of Lime on Desulphurization of Pretreated Hot Metal

Hao Huaqiang1 , Ren Qianqian1,3 , Zhang Yuzhu1,2 , Hao Suju2 , Jiang Wufeng2 , Zhang Weipan2   

  1. 1. School of Materials and Metallurgy, Northeastern University, Shenyang 110004 ;
    2. Key Laboratory of the Ministry of Education for Modem Metallurgy Technology, College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009;
    3. State Key Laboratory of Advanced Steel Process and Products,Central Iron and Steel Research Institute, Beijing 100081
  • Received:2015-11-03 Published:2016-04-01 Online:2022-08-06
  • Contact: Zhang Yuzhu

摘要: 采用比表面积1.891~2.664 m2/g和平均孔径575.5~814.9 nm四种不同结构的活性石灰在高真空电弧熔炼旋淬一体机中进行铁水预处理脱硫实验。用扫描电子显微镜分析不同石灰样品表面形貌,并用全自动压汞仪测量石灰的比表面积和平均孔径。实验结果表明铁水脱硫率随着石灰平均孔径的增大而减小,随着比表面积增大而提高;最佳脱硫剂配比为1:50。可将铁水中硫含量从0.014%脱至0.001%。

关键词: 铁水预处理, 石灰, 微观结构, 脱硫率, 脱硫剂配比

Abstract: The desulphurization test of pretreated hot metal using four different structure active limes with specific surface area 1.891-2.664 m2/g and average pore diameter 575.5-814.9 nm is carried out in a high vacuum arc melting spinning quenching machine. The surface morphology of different lime sample is analyzed by scanning electron microscope and the specific surface area and the average pore diameter of lime are measured by a fully automatic mercury injection apparatus. Experimental results show that with increasing the average hole diameter, the desulphurization rate of hot metal decreases and with increasing the specific surface area the desulphurization rate increases ; the optimum ratio of desulphurization agent is 1:50, in this case the sulphur content in hot metal decreases to 0.001 % from 0.014%.

Key words: Hot Metal Pretreatment, Lime, Microscopic Structure, Desulphurization Rate, Ratio of Desulphurization Agent