邢台钢铁有限责任公司炼钢厂,邢台,052000
[ "姬旦旦(1984-),男,硕士(2012年河北理工大学),主研工程师,2007年山西工程职业学院(本科)毕业,洁净钢生产, 工艺管理。" ]
收稿:2018-01-05,
网络首发:2022-06-02,
纸质出版:2018-06-02
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姬旦旦, 叶凡新, 张进红, 等. 含硫-铝钢GS35C-A硫化钙夹杂热力学分析和工艺改进[J]. 特殊钢, 2018,39(3):5-8.
姬旦旦, 叶凡新, 张进红, et al. Thermodynamic Analysis on Calcium Sulphide Inclusions in Bearing Sulphur-Aluminium Steel GS35C-A and Process Improvement[J]. Special Steel, 2018, 39(3): 5-8.
针对试验GS35C-A钢(/%:0.34~0.35C
0.20~0.22Si
0.69Mn
0.013~0.016P
0.026~0.045S
0.027~0.046A1
0.000 8~0.001 9Ca)夹杂物变性进行了热力学计算
并对工艺1[BOF-LF(硫合金化)-RH-钙处理-CC
]
和优化工艺2[BOF-LF-RH-钙处理-硫合金化-CC
]
对应的钢中夹杂物形貌及数量进行了研究。结果表明:(1)随着钢液中[S
]
的升高
生成CaS所需的平衡钙含量降低
钙处理变性生成低熔点夹杂物时钢液中的[Al
]
逐渐降低;(2)优化工艺2后RH离站Ca、S含量分别从优化前(工艺1)的0.001 9%和0.045%降至0.000 8%和0.026%
平均连浇炉数由原2.5炉提高至8炉;(3)优化前(工艺1)中间包典型夹杂物组分为硫化钙包裹的镁铝尖晶石
优化后(工艺2)中间包夹杂物为铝酸钙;RH离站、中间包钢中每mm
2
夹杂物个数分别从优化前9.09和6.23降至5.06和3.76。
The thermodynamic calculation on deformation of inclusions in tested steel GS35C-A (/% : 0. 34 ~0. 35C
0. 20 ~0. 22Si
0. 69Mn
0. 013 ~0. 016P
0. 026 ~0. 045S
0.027 〜0. 046Al
0.000 8 - 0.001 9Ca) has been carried out
and the morphology and amounts of inclusions in steel produced by corresponding process 1[ BOF-LF ( sulphur alloying)-RH-calcium treatment-CC
]
and optimized process 2 [BOF-LF-RH-calcium treatment- sulphur alloying- CC
]
are studied. Results show that (a) with increasing [S
]
in liquid the balancing calcium content in steel to form CaS decreases; and in process of forming low point melting inclusions modified by calcium treatment the [Al
]
in liquid gradually decreases; (b)
with decreasing end RH Ca and S content in liquid respectively from 0. 001 9% and 0. 045% ( process 1) to 0. 000 8% and 0. 026% ( optimized process 2)
the average continuous-continuous casting heats increases respectively from 2. 5 heats to 8 heats; ( c) before optimization by process 1 the typical inclusion in liquid in tundish consists of sulphide around magnesia aluminium spinel
while after optimization by process 2 the inclusion in liquid in tundish is calcium aluminate; and as compared with before optimization
after optimization the number of inclusions per mm
2
in steel at end RH and in tundish decreases respectively from 9.09 and 6.23 to 5.06 and 3.76.
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