Wu Xiaohan,Song Zhigang,He Jianguo,et al.Effect of N Content on Precipitation Behavior of Secondary Austenite in S32750 Duplex Stainless Steel[J].Special Steel,2024,45(01):18-22.
Wu Xiaohan,Song Zhigang,He Jianguo,et al.Effect of N Content on Precipitation Behavior of Secondary Austenite in S32750 Duplex Stainless Steel[J].Special Steel,2024,45(01):18-22. DOI: 10.20057/j.1003-8620.2023-00090.
Effect of N Content on Precipitation Behavior of Secondary Austenite in S32750 Duplex Stainless Steel
With the improvement of the quality and performance requirements of duplex stainless steel (DSS) in the industry, secondary austenite (γ
2
) has become one of the key factors affecting the application of S32750 DSS. Secondary austenite is considered as the joint product of temperature and cooling rates, which performed near K-S or N-W orientation relationship with the ferrite phase and an enrichment for N elements .Secondary austenite can be divided into needle-shaped austenite (NA) and isolated austenite (IA) by morphology. In this paper, the effect of N mass fraction on the precipitation behavior of secondary austenite was studied by preparing test steels with N content of 0.02%, 0.09% and 0.17%. Thermal-Calc simulation and EBSD detection proved that with the increase of N, γ
2
evolved from curved feather-shape to needled-shape with the total proportion of austenite phase increased. The precipitation mode of austenite related to the Gibbs free energy, which was namely affected by elements composition and temperature.
关键词
Keywords
references
Charles J , Chemelle P . The history of duplex developments, nowadays DSS properties and duplex market future trends [C]. Proceedings of the Duplex World Conference , Beaune, France . 2010 : 13 - 15 .
Patra S , Agrawal A , Mandal A , et al . Characteristics and manufacturability of duplex stainless steel: A review [J]. Transactions of the Indian Institute of Metals , 2021 , 74 ( 5 ): 1089 - 1098 .
Choi J Y , Park K T . Secondary austenite formation during aging of hot-rolled plate of a TRIP-aided Mo-free lean duplex stainless steel [J]. Metals and Materials International , 2021 , 27 ( 9 ): 3105 - 3114 .
Li H F , Fan G W , He Y , et al . Austenite transformation behaviour of 2205 duplex stainless steels under hot tensile test [J]. Steel Research International , 2015 , 86 ( 1 ): 84 - 88 .
Zhang Z Q , Jing H Y , Xu L Y , et al . Influence of microstructure and elemental partitioning on pitting corrosion resistance of duplex stainless steel welding joints [J]. Applied Surface Science , 2017 , 394 : 297 - 314 .
Chan K , Tjong S . Effect of secondary phase precipitation on the corrosion behavior of duplex stainless steels [J]. Materials , 2014 , 7 ( 7 ): 5268 - 5304 .
Gennari C , Pezzato L , Piva E , et al . Influence of small amount and different morphology of secondary phases on impact toughness of UNS S32205 Duplex Stainless Steel [J]. Materials Science and Engineering: A , 2018 , 729 : 149 - 156 .
Jeon S H , Kim S T , Lee I S , et al . Effects of W substitution on the precipitation of secondary phases and the associated pitting corrosion in hyper duplex stainless steels [J]. Journal of Alloys and Compounds , 2012 , 544 : 166 - 172 .
Wu X H , Song Z G , Liu L Z , et al . Effect of secondary austenite on fatigue behavior of S32750 super duplex stainless steel [J]. Materials Letters , 2022 , 322 : 132487 .
Wu X H , Song Z G , He J G , et al . Effect of newly formed Widmanstätten austenite during high temperature cooling on mechanical properties in UNS S32750 duplex stainless steel [J]. Materials Science and Engineering: A , 2022 , 851 : 143654 .
Wu X H , Song Z G , He J G , et al . The isolated austenite forming during high-temperature cooling and its influence on pitting corrosion resistance in S32750 duplex stainless steel [J]. Metals , 2022 , 12 ( 8 ): 1316 .
Wu X H , Song Z G , Wang B S , et al . Morphologies of secondary austenite in 2507 duplex stainless steel after heat treatment [J]. Journal of Iron and Steel Research International , 2022 , 29 ( 6 ): 994 - 1003 .