ISSN:1003-8620

CN:42-1243/TF

主管:中信泰富特钢集团股份有限公司

主办:大冶特殊钢有限公司

特殊钢 ›› 2024, Vol. 45 ›› Issue (3): 40-18.DOI: 10.20057/j.1003-8620.2023-00215

• 形变与相变 • 上一篇    下一篇

氮含量与终轧温度对钛微合金化高强钢 CGLC700低温冲击韧性的影响

陈玉凤1,张俊粉2,薛启河2,白 君2,杨树峰1,李京社1   

  1. (1 北京科技大学冶金与生态工程学院,北京 100083;2 河钢集团有限公司承德分公司,承德 067000)
  • 收稿日期:2023-10-26 出版日期:2024-05-30 发布日期:2024-06-01
  • 作者简介:陈玉凤(1998—),女,硕士
  • 基金资助:
    国家自然科学基金资助项目(52174311)

Effect of Nitrogen Content and Final Rolling Temperature on Low- temperature Impact Toughness of Titanium Microalloyed High- strength Steel CGLC700

Chen Yufeng1 , Zhang Junfen2 , Xue Qihe2 , Bai Jun2 , Yang Shufeng1 , Li Jingshe1   

  1. (1 School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083, China;2 Chengde Branch, HBIS Group Co., Ltd., Chengde 067000,China)
  • Received:2023-10-26 Published:2024-05-30 Online:2024-06-01

摘要: 针对钛微合金化高强钢CGLC700低温冲击韧性差的问题,通过热力学计算与高温原位观察,采用电子背散 射衍射、透射电镜、扫描电镜和光学显微镜对含Ti高强钢的夹杂物、第二相粒子、断口形貌和低温冲击韧性等进行 了研究。结果表明,含Ti高强钢低温冲击韧性差的原因与钢中大尺寸脆性夹杂物和Ti(C,N)、TiN析出相有关。将 钢中 w[N]从 0. 004 9% 降低至≤0. 003 5% 时,可以有效降低钢中脆性夹杂物的数量和尺寸,从而提高钢材冲击韧 性;终轧温度从885~895 ℃降低至875~885 ℃,可以促使纳米级TiC第二相粒子析出和大角度晶界的生成,并降低有 效晶粒尺寸,从而明显改善钢材的低温冲击韧性;同时降低氮含量至≤0. 003 5%与终轧温度在 875~885 ℃时,钛微 合金化高强钢中平均晶粒尺寸从3. 1 μm降至2. 7 μm,小尺寸有效晶粒占比高,大尺寸夹杂物及数密度降低,大角 度晶界中占比增长了16. 6%,钢材低温冲击功可以从14. 75 J提高到37. 35 J。

关键词: 钛微合金化高强钢CGLC700, 夹杂物, 第二相粒子, 低温冲击韧性, 氮含量, 终轧温度

Abstract: Aiming at the problem of poor low-temperature impact toughness of titanium microalloyed high-strength steel CGLC700, by thermodynamic calculations and high-temperature in-situ observations, as well as the use of electron back scattering diffraction, transmission electron microscopy, scanning electron microscopy, and optical microscopy have been used to investigate inclusions, second-phase particles, fracture morphology, and low-temperature impact toughness of the Ti-bearing high-strength steel. The results show that the reasons for the poor low-temperature impact toughness of Ti-bearing high-strength steel are related to the large-size brittle inclusions and the precipitation phase of Ti(C,N) and TiN in the steel. When the nitrogen content in steel is reduced from 0. 004 9% to ≤0. 003 5%, the number and size of brittle in clusions in steel can be effectively reduced, and the impact toughness of steel can be improved. Reducing the final rolling temperature from 885-895 ℃ to 875-885 °C can promote the precipitation of nanoscale TiC second phase particles and the formation of large-angle grain boundaries, and reduce the effective grain size, thereby significantly improving the low-temperature impact toughness of steel. Compared with experimental steel 1#, when the nitrogen content was reduced to ≤ 0. 003 5% and the final rolling temperature was 875-885 °C, the average grain size in titanium microalloyed high-strength steel decreased from 3. 1 μm to 2. 7 μm, the proportion of small-size effective grains was higher, the large-size inclusions and number density decreased, the proportion in the large-angle grain boundary increased by 16. 6%, and the low-temperature impact energy of steel could be increased from 14. 75 J to 37. 35 J.

Key words: Titanium Microalloyed High Strength Steel CGLC700, Inclusions, Second Phase Particles, Lowtemperature Impact Toughness, Nitrogen Content, Final Rolling Temperature

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