ISSN:1003-8620

CN:42-1243/TF

Governed by: CITIC Pacific Special Steel Group Co., LTD

Sponsored by: Daye Special Steel Co., LTD.

Special Steel ›› 2007, Vol. 28 ›› Issue (1): 4-6.

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Formulae of Equilibrium Solid Solubility of Fe4N and Nitrogen in Iron Matrix

Yong Qilong1, Chen Mingxin1, Zhao Kunyu2, Cao Jianchun2   

  1. 1 Central Iron and Steel Research Institute, Beijing 100081;
    2 Kunming University of Science and Technology, Kunming 650093
  • Received:2006-06-12 Online:2007-01-01 Published:2023-01-12

Fe4N及氮在铁基体中的平衡固溶度公式

雍岐龙1, 陈明昕1, 赵昆渝2, 曹建春2   

  1. 1钢铁研究总院结构材料所,北京100081 ;
    2昆明理工大学,昆明650093
  • 作者简介:雍岐龙(1953-),男,教授,结构所副总工程师,钢铁材料基础理论研究。
  • 基金资助:
    国家自然科学基金项目资助(50441032)

Abstract: According to measured solubility data of Thermo-Calc and concerned references, the equilibrium solid solubility formulae of Fe4N in austenite and in ferrite have been derived respectively as log[N] γ= 0.940 -479.4/T and log[N]α= 1.074 - 1 838/T. With considering free energy of Fe4N formation, the equilibrium solid solubility formulae of nitrogen (gas) in austenite and in ferrite have been derived respectively as log[N] γ= -2.752 + 1 321/T and log[N] α= -1.560-1 214/T.

摘要: 根据Thermo-Calc和相关文献的测试数据,推导出Fe4N在奥氏体和铁素体中的平衡固溶度公式分别:log[N]γ= 0.940 - 479.4/T, log[ N]α= 1.074 - 1 838/T。 同时考虑Fe4N的形成自由能而推导出氮(气)在奥氏 体和铁素体中的平衡固溶度公式分别为:log[N]γ= -2.752 + 1321/T, log[N]α= -1.560-1214/T。