Analysis on Thermodynamics of BOF Smelting Ultra-Low Phosphorous Steel by CaO Series Slag Adding Lepidolite and Commercial Test
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Analysis on Thermodynamics of BOF Smelting Ultra-Low Phosphorous Steel by CaO Series Slag Adding Lepidolite and Commercial Test
Special SteelVol. 37, Issue 3, Pages: 13-19(2016)
作者机构:
1. 北京科技大学冶金与生态工程学院,北京,100081
2. 钢铁研究总院连铸技术国家工程研究中心,北京,100083
3. 河北钢铁股份有限公司承德分公司,承德,067002
作者简介:
基金信息:
DOI:
CLC:
Received:13 December 2015,
Online First:02 August 2022,
Published:02 August 2016
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张明博, 仇圣桃, 朱荣, et al. Analysis on Thermodynamics of BOF Smelting Ultra-Low Phosphorous Steel by CaO Series Slag Adding Lepidolite and Commercial Test[J]. Special Steel, 2016, 37(3): 13-19.
DOI:
张明博, 仇圣桃, 朱荣, et al. Analysis on Thermodynamics of BOF Smelting Ultra-Low Phosphorous Steel by CaO Series Slag Adding Lepidolite and Commercial Test[J]. Special Steel, 2016, 37(3): 13-19.DOI:
Analysis on Thermodynamics of BOF Smelting Ultra-Low Phosphorous Steel by CaO Series Slag Adding Lepidolite and Commercial Test
It is obtained by coexistence theory calculation and thermodynamics analysis that the slag-steel phosphorus partition ratio Lp of compound dephosphorizing slag CaO-MgO-FeO-Li
2
O-Na
2
O-K2O-SiO
2
-P
2
O
5
is obviously higher than that of basic dephosphorizing slag series CaO-MgO-FeO-SiO
2
-P
2
O
5
and defined that the optimum adding lepidolite period is the early stage of BOF blowing. The results of 10 heats 120 t BOF smelting ultra-low phosphorus steel show that as compared with the heats non-adding lepidolite
the semisteel [P
]
of heats by adding lepidolite decreases quickly to less than 0. 044%
the semi-steel dephosph
orization ratio and phosphorus partition ratio Lp respectively increase from 40. 62% and 13.13 to 67.71% and 36. 89
and the BOF average end dephosphorization ratio and phosphorus partition increase respectively from 92.35% and 130.7 to 94. 85% and 191.9
and the BOF end [P
]
can be controlled in 0.005% ~0. 007% with [P
]
percentage of hits 100%
so the compound slag series meet the requirement of ultra-low phosphorus steel production.