ISSN:1003-8620
CN:42-1243/TF
Governed by: CITIC Pacific Special Steel Group Co., LTD
Sponsored by: Daye Special Steel Co., LTD.
Special Steel ›› 2018, Vol. 39 ›› Issue (3): 5-8.
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Ji Dandan, Ye Fanxin, Zhang Jinhong, Dai Yonggang , Li Fuwei
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姬旦旦,叶凡新 ,张进红,戴永刚, 李富伟
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Abstract: The thermodynamic calculation on deformation of inclusions in tested steel GS35C-A (/% : 0. 34 ~0. 35C, 0. 20 ~0. 22Si, 0. 69Mn, 0. 013 ~0. 016P, 0. 026 ~0. 045S, 0.027 〜0. 046Al, 0.000 8 - 0.001 9Ca) has been carried out, and the morphology and amounts of inclusions in steel produced by corresponding process 1[ BOF-LF ( sulphur alloying)-RH-calcium treatment-CC] and optimized process 2 [BOF-LF-RH-calcium treatment- sulphur alloying- CC] are studied. Results show that (a) with increasing [S] in liquid the balancing calcium content in steel to form CaS decreases; and in process of forming low point melting inclusions modified by calcium treatment the [Al] in liquid gradually decreases; (b) with decreasing end RH Ca and S content in liquid respectively from 0. 001 9% and 0. 045% ( process 1) to 0. 000 8% and 0. 026% ( optimized process 2) , the average continuous-continuous casting heats increases respectively from 2. 5 heats to 8 heats; ( c) before optimization by process 1 the typical inclusion in liquid in tundish consists of sulphide around magnesia aluminium spinel, while after optimization by process 2 the inclusion in liquid in tundish is calcium aluminate; and as compared with before optimization, after optimization the number of inclusions per mm2 in steel at end RH and in tundish decreases respectively from 9.09 and 6.23 to 5.06 and 3.76.
Key words:  , Bearing Sulphur-Aluminium Steel GS35C-A, Thermal Calculation, Calcium Treatment, Calcium Sulphide, Application
摘要: 针对试验GS35C-A钢(/%:0.34~0.35C,0.20~0.22Si,0.69Mn,0.013~0.016P,0.026~0.045S,0.027~0.046A1,0.000 8~0.001 9Ca)夹杂物变性进行了热力学计算,并对工艺1[BOF-LF(硫合金化)-RH-钙处理-CC]和优化工艺2[BOF-LF-RH-钙处理-硫合金化-CC]对应的钢中夹杂物形貌及数量进行了研究。结果表明:(1)随着钢液中[S]的升高,生成CaS所需的平衡钙含量降低,钙处理变性生成低熔点夹杂物时钢液中的[Al]逐渐降低;(2)优化工艺2后RH离站Ca、S含量分别从优化前(工艺1)的0.001 9%和0.045%降至0.000 8%和0.026%,平均连浇炉数由原2.5炉提高至8炉;(3)优化前(工艺1)中间包典型夹杂物组分为硫化钙包裹的镁铝尖晶石,优化后(工艺2)中间包夹杂物为铝酸钙;RH离站、中间包钢中每mm2夹杂物个数分别从优化前9.09和6.23降至5.06和3.76。
Ji Dandan, Ye Fanxin, Zhang Jinhong, Dai Yonggang , Li Fuwei. Thermodynamic Analysis on Calcium Sulphide Inclusions in Bearing Sulphur-Aluminium Steel GS35C-A and Process Improvement[J]. Special Steel, 2018, 39(3): 5-8.
姬旦旦, 叶凡新, 张进红, 戴永刚, 李富伟. 含硫-铝钢GS35C-A硫化钙夹杂热力学分析和工艺改进[J]. 特殊钢, 2018, 39(3): 5-8.
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