ISSN:1003-8620

CN:42-1243/TF

Governed by: CITIC Pacific Special Steel Group Co., LTD

Sponsored by: Daye Special Steel Co., LTD.

Special Steel ›› 2023, Vol. 44 ›› Issue (3): 53-58.DOI: 10.20057/j.1003-8620.2022-00220

Special Issue: 连铸工艺

• Smelting and Solidification • Previous Articles     Next Articles

Development of Mold Flux for Continuous Casting of Cr13 Type Martensitic Stainless Steel Square Billet

Feng Weimin1, Xue Jingheng2, Xing Guocheng2, Ren Fei2, Wang Hongpo3, Wang Yu3   

  1. 1 Jiangsu Citicsteel- Chianaref new materials institute Co., Ltd., Wuxi 214266;
    2 Fushun Special Steel Co., Ltd., Fushun 113001;
    3 College of Materials Science and Engineering, Chongqing University, Chongqing 400044
  • Received:2023-01-18 Online:2023-06-01 Published:2023-05-17

Cr13型马氏体不锈钢方坯连铸保护渣的开发

冯为民1, 薛井恒2, 邢国成2, 任飞2, 王宏坡3, 王雨3   

  1. 1 江苏中特嘉耐新材料研究院有限公司, 无锡 214266;
    2 抚顺特殊钢股份有限公司, 抚顺 113001;
    3 重庆大学材料科学与工程学院, 重庆 400030
  • 作者简介:冯为民(1966-),男,工程师

Abstract: The surface depressions and longitudinal cracks of 2Cr13, 3Cr13, and 4Cr13 casting billets produced through 4-machine and 4-strand continuous casting machines in a special steel plant were analyzed and studied, the surface depression and longitudinal cracks of Cr13 stainless steel billet were solved by processing measures. Pre-melting mold flux consisting of 28%-31% SiO2 , 28%-31% CaO , 6%-9% Al2O3 , 7%-10% Na2O and 3%-6% F- were used, and comprehensive carbon preparation, especially the addition of carbon black was increased; the total carbon content was 15%-18%. The basicity of mold flux was controlled at about 1.0, the melting temperature was 1130-1150 ℃, and the viscosity at 1300 ℃ was 0.40-0.55 Pa·s. The turning temperature of the mold flux was 1140-1180 ℃, and the crystallization rate was about 48.8%. The superheat of 2Cr13 liquid steel in the tundish should be less than 30 ℃, and the superheat of 3Cr13 and 4Cr13 liquid steel should be less than 35 ℃. Automatic slagging is adopted in continuous casting process to control appropriate slag layer thickness and keep liquid level stable.

Key words: Cr13 Martensitic Stainless Steel, Continuous Casting, Longitudinal Cracking, Mold Flux

摘要: 针对特钢厂4机4流连铸机生产的2Cr13、3Cr13、4Cr13铸坯表面凹陷、纵裂缺陷进行分析和研究,通过工艺措施解决了Cr13型马氏体不锈钢铸坯的表面凹陷和纵裂问题。采用预熔型保护渣,其中SiO2和CaO均为28%~31%、Al2O3为6%~9%、Na2O为7%~10%、F-为3%~6%,以及综合配碳,尤其是增加炭黑的加入量,总C含量为15%~18%。保护渣碱度控制在1.0左右,熔化温度为1130~1150 ℃,1300 ℃时黏度为0.40~0.55 Pa·s;保护渣转折温度为1140~1180 ℃,结晶率约为48.8% 。控制中间包内2Cr13钢液过热度≤30 ℃,3Cr13和4Cr13钢液过热度≤35 ℃;连铸过程中采用自动加渣方式,控制适宜的渣层厚度并保持液面稳定。

关键词: Cr13型马氏体不锈钢, 连铸, 纵裂, 保护渣