1.安徽工业大学材料科学与工程学院,马鞍山 243032
2.安徽省金属材料与加工重点实验室,马鞍山 243032
3.敬业(营口)中板有限公司冶金技术处,营口 115005
4.安徽工业大学冶金工程学院, 马鞍山 243032
李鑫(1985—),男,硕士生; E-mail : lixin_ahut@163.com
王永强(1982—),男,博士,教授; E-mail : yqwang@ahut.edu.cn;
收稿:2025-07-24,
纸质出版:2026-03-30
移动端阅览
李鑫,史晓斌,王永强等.中厚板生产研发及其低温冲击韧性研究概况[J].特殊钢,2026,47(02):1-12.
Li Xin,Shi Xiaobin,Wang Yongqiang,et al.Overview of Production and Research of Medium and Heavy Plates and Low Temperature Impact Toughness[J].Special Steel,2026,47(02):1-12.
李鑫,史晓斌,王永强等.中厚板生产研发及其低温冲击韧性研究概况[J].特殊钢,2026,47(02):1-12. DOI: 10.20057/j.1003-8620.2025-00176.
Li Xin,Shi Xiaobin,Wang Yongqiang,et al.Overview of Production and Research of Medium and Heavy Plates and Low Temperature Impact Toughness[J].Special Steel,2026,47(02):1-12. DOI: 10.20057/j.1003-8620.2025-00176.
随着我国“一带一路”战略的不断推进以及能源基础建设、造船领域的快速发展,作为制造容器/压力容器、船舶、管线等的主要材料—中厚板的需求越来越大,其力学性能要求也越来越高。低温冲击韧性是其中最为重要的性能指标之一。因厚度大,低温冲击韧性值通常表现出明显的离散性、波动性,是中厚板产品面临的主要质量问题之一。首先,归纳了中厚板的轧制生产工艺、关键制造技术以及力学和工艺性能要求。随着使用要求的提高和生产装备及技术的进步,中厚板的尺寸和性能要求也越来越大、越来越高;目前中厚板产品的最大厚度可达700 mm,稳定生产的高性能耐磨钢板的抗拉强度已高达1 900 MPa,1 300 MPa级别的高强机械用钢也已实现供货。然后,在此基础上,重点总结了国内外学者关于中厚板低温冲击韧性研究情况,包括产生机理(原因)、影响因素、改善方法等;低温韧性波动的主要原因是组织的不均匀性,通过成分和工艺优化提高组织均匀性可解决低温冲击波动问题。最后,指出了目前低温冲击韧性研究存在的不足以及中厚板产品开发和生产技术的未来发展方向。
With the rapid development of energy infrastructure, shipbuilding and promotion of China’s “the Belt and Road” strategy, the demand for medium and heavy plates that widely used for containers/pressure vessels, ships, pipelines, etc.,is growing increasingly, and their mechanical properties are also increasingly demanding. Low temperature impact toughness is one of the most important performance indicators. Due to the large thickness, the low temperature toughness value is usually discrete and fluctuating, which is one of the main issues for medium and heavy plate products. In this paper, the main rolling technologies, key manufacturing technologies and mechanical and process performance requirement for medium and heavy plate were reviewed firstly. With the increasing demands for usage and advancements in production equipment and technologies, the requirements for the size and mechanical properties of medium and heavy plates are becoming larger and higher, respectively. Currently, the maximum thickness of heavy plate products can reach 700 mm, and the tensile strength of stably produced high-performance wear-resistant steel plates has reached up to 1 900 MPa, the 1 300 MPa level high strength mechanical steels has also been supplied at the market. And then, the research progress on low temperature toughness of medium and heavy plates, including mechanism, influence factors, and improvement methods, were summarized. The main reason of low temperature toughness fluctuations is the heterogeneity of the microstructures. Improving the homogeneity of the microstructures through composition and process optimization can mitigate the fluctuation of low-temperature impact. Finally, the insufficient aspects for the research on low temperature impact toughness of medium and heavy plate and the future development direction of the technology were pointed out.
中华人民共和国国家质量监督检验检疫总局 , 中国国家标准化管理 . 钢产品分类 [P]. GB/T 15574-2016 , 2016 .
唐 荻 , 武会宾 . 我国高附加值中厚板产品现状与发展趋势 [J]. 轧钢 , 2012 , 29 ( 4 ): 1 - 4 .
陈永利 , 罗 登 , 杨来铭 , 等 . 中厚板市场的发展现状及趋势 [J]. 钢铁研究学报 , 2009 , 21 ( 7 ): 1 - 4 .
袁 国 , 王国栋 , 王日清 , 等 . 中厚钢板热处理技术及设备发展概况 [J]. 钢铁研究学报 , 2009 , 21 ( 5 ): 1 - 7 .
田 勇 , 王丙兴 , 袁国 , 等 . 基于超快冷技术的新一代中厚板轧后冷却工艺 [J]. 中国冶金 , 2013 , 23 ( 4 ): 17 - 20+34 .
王国栋 . 新一代TMCP技术的发展 [J]. 中国冶金 , 2012 , 22 ( 12 ): 1 - 5 .
王国栋 . 高质量中厚板生产关键共性技术研发现状和前景 [J]. 轧钢 , 2019 , 36 ( 1 ): 1 - 8+30 .
朱伏先 , 肖桂枝 , 陈炳张 , 等 . 直接淬火技术在中厚钢板生产中的工业应用 [J]. 钢铁研究学报 , 2010 , 22 ( 7 ): 1 - 5 .
任树洋 , 尹绍江 , 李 行 , 等 . 新一代中厚板制造关键技术在唐钢的应用 [J]. 中国冶金 , 2019 , 29 ( 9 ): 60 - 67 .
朱苗勇 . 新一代高效连铸技术发展思考 [J]. 钢铁 , 2019 , 54 ( 8 ): 21 - 36 .
矫志杰 , 何纯玉 , 丁敬国 , 等 . 中厚板轧机平面形状控制技术的工业推广应用 [J]. 钢铁 , 2019 , 54 ( 1 ): 49 - 55 .
邹 鑫 , 胡 宇 , 宋向荣 , 等 . 中厚板轧制过程侧弯模型及控制策略 [J]. 钢铁研究学报 , 2015 , 27 ( 3 ): 35 - 39 .
冀秀梅 , 王 龙 , 高克伟 , 等 . 极限学习机在中厚板轧制力预报中的应用 [J]. 钢铁研究学报 , 2020 , 32 ( 5 ): 393 - 399 .
王国栋 . 新一代TMCP技术的发展 [J]. 轧钢 , 2012 , 29 ( 1 ): 1 - 8 .
袁 国 , 陈 冬 , 康 健 , 等 . 大型热连轧线基于超快速冷却的新一代控轧控冷技术开发与应用 [J]. 钢铁研究学报 , 2019 , 31 ( 2 ): 150 - 158 .
刘振宇 , 唐 帅 , 周晓光 , 等 . 新一代TMCP工艺下热轧钢材显微组织的基本原理 [J]. 中国冶金 , 2013 , 23 ( 4 ): 10 - 16 .
李 凡 , 衣海龙 , 陈军平 , 等 . 超快冷技术在鞍钢Q550工程机械用钢生产中的应用 [J]. 轧钢 , 2011 , 28 ( 5 ): 7 - 8+50 .
郑东升 . 超快冷技术在TMCP钢种工业化生产中的应用 [J]. 宽厚板 , 2016 , 22 ( 6 ): 23 - 27 .
张阔斌 , 侯 蕾 , 王 俊 , 等 . 超快冷技术在唐钢中厚板生产线上的应用 [J]. 轧钢 , 2018 , 35 ( 5 ): 67 - 70 .
王 新 , 陈小林 , 田士平 , 等 . 超快冷技术在首秦宽厚板生产线上的应用 [J]. 钢铁研究学报 , 2011 , 23 ( S1 ): 11 - 14 .
国家市场监督管理总局 , 国家标准化管理委员会 . 船舶及海洋工程用结构钢 [P] GB/T 712-2022 , 2022 .
中华人民共和国国家质量监督检验检疫总局 , 中国国家标准化管理委员会 . 锅炉和压力容器用钢板 [P]. GB713-2014 , 2014 .
中华人民共和国国家质量监督检验检疫总局 , 中国国家标准化管理委员会 . 压力容器用调质高强钢板 [P]. GB 19189-2011 , 2011 .
中华人民共和国国家质量监督检验检疫总局 , 中国国家标准化管理委员会 . 低温压力容器用钢板 [P]. GB 3531-2014 , 2014 .
国家市场监督管理总局 , 国家标准化管理委员会 . 金属材料弯曲试验方法 [P]. GB/T 232-2024 , 2024 .
Reiser J , Hoffmann J , Jäntsch U , et al . Ductilisation of tungsten (W): On the shift of the brittle-to-ductile transition (BDT) to lower temperatures through cold rolling [J]. International Journal of Refractory Metals and Hard Materials , 2016 , 54 : 351 - 369 .
Kameda J . A kinetic model for ductile-brittle fracture mode transition behavior [J]. Acta Metallurgica , 1986 , 34 ( 12 ): 2391 - 2398 .
Zhang Y H , Han W Z . Mechanism of brittle-to-ductile transition in tungsten under small-punch testing [J]. Acta Materialia , 2021 , 220 : 117332 .
Németh A A N , Reiser J , Armstrong D E J , et al . The nature of the brittle-to-ductile transition of ultra fine grained tungsten (W) foil [J]. International Journal of Refractory Metals and Hard Materials , 2015 , 50 : 9 - 15 .
Lu Y , Zhang Y H , Ma E , et al . Relative mobility of screw versus edge dislocations controls the ductile-to-brittle transition in metals [J]. Proceedings of the National Academy of Sciences of the United States of America , 2021 , 118 ( 37 ): e2110596118 .
Song M , Zhu R , Foley D C , et al . Enhancement of strength and ductility in ultrafine-grained T91 steel through thermomechanical treatments [J]. Journal of Materials Science , 2013 , 48 ( 21 ): 7360 - 7373 .
Sun B , Kwiatkowski da Silva A , Wu Y , et al . Physical metallurgy of medium-Mn advanced high-strength steels [J]. International Materials Reviews , 2023 , 68 ( 7 ): 786 - 824 .
Li D Z , Wang B J , Shen X J , et al . Excellent low-temperature toughness of 1 GPa grade microlaminated 5Mn steel containing retained austenite [J]. Materials Science and Engineering: A , 2024 , 895 : 146251 .
Wang Y W , Wang H H , Su Y H , et al . Cryogenic impact fracture behavior of a high-Mn austenitic steel using electron backscatter diffraction and neutron Bragg-edge transmission imaging [J]. Materials Science and Engineering: A , 2023 , 887 : 145768 .
那顺桑 , 姚青芳 . 金属强韧化原理与应用 [M]. 北京 : 化学工业出版社 , 2006 .
Speer J , Matlock D K , De Cooman B C , et al . Carbon partitioning into austenite after martensite transformation [J]. Acta Materialia , 2003 , 51 ( 9 ): 2611 - 2622 .
万德成 , 余 伟 , 李晓林 , 等 . DQP工艺在高强韧中厚板生产中的应用研究 [J]. 钢铁研究学报 , 2011 , 23 ( S1 ): 1 - 5 .
Sun Y , Hu S , Xiao Z , et al . Effects of nickel on low-temperature impact toughness and corrosion resistance of high-ductility ductile iron [J]. Materials & Design , 2012 , 41 : 37 - 42 .
王龙妹 . 稀土在低合金及合金钢中的应用 [M]. 北京 : 冶金工业出版社 , 2016 .
王龙妹 , 杜 挺 , 卢先利 , 等 . 微量稀土元素在钢中的作用机理及应用研究 [J]. 稀土 , 2001 , 22 ( 4 ): 37 - 40 .
李 娜 , 陆勤阳 , 王永强 , 等 . Ce对2.9%Si-0.8%Al无取向硅钢夹杂物变质的影响 [J]. 钢铁研究学报 , 2017 , 29 ( 7 ): 570 - 576 .
武利平 , 刘 妍 , 智建国 , 等 . 稀土Ce对C-Mn低温钢强韧性的影响机制 [J]. 稀有金属材料与工程 , 2022 , 51 ( 12 ): 4561 - 4569 .
武利平 , 张江山 , 智建国 , 等 . 稀土La+Ce对含Nb结构钢强度及韧性的影响 [J]. 稀有金属材料与工程 , 2020 , 49 ( 8 ): 2800 - 2806 .
瞿 伟 , 任慧平 , 金自力 , 等 . 稀土镧对低合金高强钢微观组织及冲击韧性的影响 [J]. 稀有金属材料与工程 , 2018 , 47 ( 7 ): 2087 - 2092 .
文 智 , 易丹青 , 王 斌 , 等 . 稀土对T91耐热钢动态再结晶行为影响 [J]. 北京科技大学学报 , 2013 , 35 ( 8 ): 1000 - 1006 .
Chu R S , Fan Y , Li Z J , et al . Study on the control of rare earth metals and their behaviors in the industrial practical production of Q420q structural bridge steel plate [J]. Metals , 2018 , 8 ( 4 ): 240 .
Lan J , He J J , Ding W J , et al . Effect of rare earth metals on the microstructure and impact toughness of a cast 0.4C-5Cr-1.2Mo-1.0V steel [J]. ISIJ International , 2000 , 40 ( 12 ): 1275 - 1282 .
Jiang Z H , Wang P , Li D Z , et al . Effects of rare earth on microstructure and impact toughness of low alloy Cr-Mo-V steels for hydrogenation reactor vessels [J]. Journal of Materials Science & Technology , 2020 , 45 : 1 - 14 .
Zhou C , Ye Q B , Hu J , et al . Ultra-high-strength multi-alloyed steel with enhanced cryogenic toughness using thermally stable retained austenite [J]. Materials Science and Engineering: A , 2022 , 831 : 142356 .
Jiang L , Wang J , Zhang T , et al . Superior low temperature toughness in a newly designed low Mn and low Ni high strength steel [J]. Materials Science and Engineering: A , 2021 , 825 : 141899 .
Xie Z , Shang C , Zhou W , et al . Effect of retained austenite on ductility and toughness of a low alloyed multiphase steel [J]. Acta Metallurgica Sinica , 2016 , 52 ( 2 ): 224 - 232 .
Gao G H , Zhang H , Gui X L , et al . Enhanced ductility and toughness in an ultrahigh-strength Mn-Si-Cr-C steel: The great potential of ultrafine filmy retained austenite [J]. Acta Materialia , 2014 , 76 : 425 - 433 .
韩卫忠 , 卢 岩 , 张雨衡 . 体心立方金属韧脆转变机制研究进展 [J]. 金属学报 , 2023 , 59 ( 3 ): 335 - 348 .
高 潇 , 杨仁杰 , 李英杰 , 等 . 带状组织对Q345E钢力学性能的影响 [J]. 大型铸锻件 , 2016 ( 2 ): 29 - 31 .
王 强 , 刘忠满 , 郑治秀 , 等 . 改善Q345E中厚钢板低温冲击韧性实践研究 [J]. 宽厚板 , 2021 , 27 ( 1 ): 21 - 24 .
Tsuji N , Okuno S , Koizumi Y , et al . Toughness of ultrafine grained ferritic steels fabricated by ARB and annealing process [J]. Materials Transactions , 2004 , 45 ( 7 ): 2272 - 2281 .
Takaki S , Kawasaki K , Kimura Y . Mechanical properties of ultra fine grained steels [J]. Journal of Materials Processing Technology , 2001 , 117 ( 3 ): 359 - 363 .
沈俊昶 , 罗志俊 , 杨才福 , 等 . 低合金钢板条组织中影响低温韧性的“有效晶粒尺寸” [J]. 钢铁研究学报 , 2014 , 26 ( 7 ): 70 - 76 .
Petch N J . The ductile-brittle transition in the fracture of α-iron: I [J]. Philosophical Magazine , 1958 , 3 ( 34 ): 1089 - 1097 .
Ovid’ko I A , Valiev R Z , Zhu Y T . Review on superior strength and enhanced ductility of metallic nanomaterials [J]. Progress in Materials Science , 2018 , 94 : 462 - 540 .
Lin T , Evans A G , Ritchie R O . Stochastic modeling of the independent roles of particle size and grain size in transgranular cleavage fracture [J]. Metallurgical Transactions A , 1987 , 18 ( 4 ): 641 - 651 .
Chen J H , Li G , Cao R , et al . Micromechanism of cleavage fracture at the lower shelf transition temperatures of a C-Mn steel [J]. Materials Science and Engineering: A , 2010 , 527 ( 18-19 ): 5044 - 5054 .
Bose Filho W W , Carvalho A L M , Bowen P . Micromechanisms of cleavage fracture initiation from inclusions in ferritic welds Part I. Quantification of local fracture behaviour observed in notched testpieces [J]. Materials Science and Engineering: A , 2007 , 460 : 436 - 452 .
Cao R , Li G , Fang X Y , et al . Investigation on the effects of microstructure on the impact and fracture toughness of a C-Mn steel with various microstructures [J]. Materials Science and Engineering: A , 2013 , 564 : 509 - 524 .
武利平 . 稀土Ce对低温容器钢微观组织及低温韧性的作用机制研究 [D]. 北京科技大学 , 2022 .
石 昆 . 大型低温球罐用07MnNiMoDR钢的组织与低温韧性离散性的研究 [D]. 上海 : 上海交通大学 , 2016 .
Chen J H , Zhu L , Ma H . On the scattering of the local fracture stress σ f [J]. Acta Metallurgica et Materialia , 1990 , 38 ( 12 ): 2527 - 2535 .
Bouchard R , Shen G , Tyson W R . Fracture toughness variability of structural steel [J]. Engineering Fracture Mechanics , 2008 , 75 ( 12 ): 3735 - 3742 .
Beremin F M , Pineau A , Mudry F , et al . A local criterion for cleavage fracture of a nuclear pressure vessel steel [J]. Metallurgical Transactions A , 1983 , 14 ( 11 ): 2277 - 2287 .
Karthikeyan T , Thomas Paul V , Saroja S , et al . Grain refinement to improve impact toughness in 9Cr-1Mo steel through a double austenitization treatment [J]. Journal of Nuclear Materials , 2011 , 419 ( 1-3 ): 256 - 262 .
Shi K , Chen J B , Hou H , et al . Impact toughness scattering of bainitic steel in the ductile-brittle transition temperature region [J]. Journal of Wuhan University of Technology-Mater Sci Ed , 2016 , 31 ( 3 ): 636 - 643 .
张海军 , 高 雅 , 刘利香 , 等 . 压力容器用07MnNiMoDR钢板的低温冲击韧性研究 [J]. 河南冶金 , 2014 , 22 ( 1 ): 16 - 18 .
赵全卿 , 王志明 , 刘 生 , 等 . 提高07MnNiMoDR钢板性能合格率的工艺实践 [J]. 宽厚板 , 2014 , 20 ( 2 ): 18 - 19+23 .
李样兵 , 柳付芳 , 李 杰 , 等 . 大厚度严要求 14 Cr 1 MoR钢最佳热处理制度探究 [J]. 中国冶金 , 2021 , 31 ( 2 ): 76 - 83 .
李样兵 , 柳付芳 , 赵国昌 , 等 . 14Cr 1 MoR钢136 mm特厚板极限低温冲击韧性 [J]. 特殊钢 , 2020 , 41 ( 4 ): 59 - 63 .
Jiang S H , Wang H , Wu Y , et al . Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation [J]. Nature , 2017 , 544 ( 7651 ): 460 - 464 .
王永强 , 朱国辉 , 陈其伟 , 等 . 高强度超细晶金属材料塑性行为及增塑研究进展 [J]. 材料导报 , 2018 , 32 ( 19 ): 3414 - 3422 .
Zhao Y H , Liao X Z , Cheng S , et al . Simultaneously increasing the ductility and strength of nanostructured alloys [J]. Advanced Materials , 2006 , 18 ( 17 ): 2280 - 2283 .
Yang G , Huang C X , Wang C , et al . Enhancement of mechanical properties of heat-resistant martensitic steel processed by equal channel angular pressing [J]. Materials Science and Engineering: A , 2009 , 515 ( 1-2 ): 199 - 206 .
吕昭平 , 蒋虽合 , 何骏阳 , 等 . 先进金属材料的第二相强化 [J]. 金属学报 , 2016 , 52 ( 10 ): 1183 - 1198 .
Kim S H , Kim H , Kim N J . Brittle intermetallic compound makes ultrastrong low-density steel with large ductility [J]. Nature , 2015 , 518 ( 7537 ): 77 - 79 .
Raabe D , Ponge D , Dmitrieva O , et al . Nanoprecipitate-hardened 1.5GPa steels with unexpected high ductility [J]. Scripta Materialia , 2009 , 60 ( 12 ): 1141 - 1144 .
NANOSTEEL . https://nanosteelco.com/products/sheet-steel/new-class-of-steel, 2012 .
Guo Z , Lee C S , Morris J W . On coherent transformations in steel [J]. Acta Materialia , 2004 , 52 ( 19 ): 5511 - 5518 .
Lambert-Perlade A , Gourgues A F , Besson J , et al . Mechanisms and modeling of cleavage fracture in simulated heat-affected zone microstructures of a high-strength low alloy steel [J]. Metallurgical and Materials Transactions A , 2004 , 35 ( 13 ): 1039 - 1053 .
Duan H , Shan Y Y , Yang K , et al . Effect of microstructure and crystallographic orientation characteristics on low temperature toughness and fracture behavior of pipeline steels [J]. Journal of Materials Research and Technology , 2022 , 17 : 3172 - 3185 .
Flower H M , Lindley T C . Electron backscattering diffraction study of acicular ferrite, bainite, and martensite steel microstructures [J]. Materials Science and Technology , 2000 , 16 ( 1 ): 26 - 40 .
Zhang Y H , Guo X C , Fu B G , et al . Microstructure and low-temperature impact fracture behavior of QT400-18AL containing Ni [J]. Materials Science and Engineering: A , 2023 , 880 : 145327 .
Wang Y Q , Hu C J , Tian K , et al . Excellent ductility of an austenitic stainless steel at a high strength level achieved by a simple process [J]. Materials & Design , 2024 , 239 : 112796 .
由 洋 , 王学敏 , 尚成嘉 . 奥氏体化温度对HSLA100高强度低合金钢组织及冲击韧性的影响 [J]. 金属学报 , 2012 , 48 ( 11 ): 1290 - 1298 .
0
浏览量
0
下载量
0
CSCD
0
CNKI被引量
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621