时彦林, 张士宪. Study on Metallurgical Kinetics of Blowing Nitrogen Alloying of Ultra-Low Carbon Austenite Stainless Steel 316L and Application[J]. Special Steel, 2017, 38(3): 28-32.
时彦林, 张士宪. Study on Metallurgical Kinetics of Blowing Nitrogen Alloying of Ultra-Low Carbon Austenite Stainless Steel 316L and Application[J]. Special Steel, 2017, 38(3): 28-32.DOI:
According to double film theory the kinetics model of blowing nitrogen alloying in steel liquid during stainless steel refining is established. By using silicon-molybdenum bar furnace the effect of nitrogen blowing time (0~70 min)
nitrogen partial pressure (N
2
:Ar = 2 : 1
1:2 and 1:1) and temperature (1773~1833K) with constant pressure (101kPa)
constant temperature 1833K and constant flow rate 0.3L/min on nitrogen alloying of stainless steel 316L(/%: 0.031C
0.57Si
1.00Mn
0.921P
0.004S
16.13Cr
10.12N
2.12Mo
0.028N) has been studied. Results show that with increasing nitrogen blowing time and nitrogen partial pressure the nitrogen content in steel increases;with increasing nitrogen flow rate the blowing time for nitrogen conten
t in liquid up to saturating value decreases;with decreasing liquid temperature the dissolvability of nitrogen in steel increases
and the suitable temperature of liquid is 1500°C. The 120t VOD commercial pilot production of stainless steel 316L show that by blowing nitrogen alloying during VOD vacuum period with nitrogen flow rate 42x3m
3
/h the nitrogen content in steel may be up to 0.04%.