ISSN:1003-8620

CN:42-1243/TF

Governed by: CITIC Pacific Special Steel Group Co., LTD

Sponsored by: Daye Special Steel Co., LTD.

Special Steel ›› 2024, Vol. 45 ›› Issue (6): 57-61.DOI: 10.20057/j.1003-8620.2024-00024

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Ractice of EF3 Ultra-low Phosphorus Smelting Process for High-grade Pipeline Welding Wire

Zhang Xingli, Qi Fengyou, Su Yongze, Cui Guibo, Tang Qing, Hou Jianwei   

  1. (Qingdao Branch , CITIC Pacific Steel Research Institute,Qingdao 266000,China)
  • Received:2024-01-26 Online:2024-11-30 Published:2024-12-01

高级别管线用焊丝EF3超低磷冶炼工艺实践

张行利, 亓奉友, 苏永泽, 崔贵博, 唐庆, 侯建伟   

  1. (中信泰富特钢研究院青钢分院,青岛 266000)
  • 作者简介: 张行利(1990—),男,本科,工程师

Abstract:  In order to realize the stable batch production of ultra-low P welding wire EF3 for high-grade pipelines, the conditions of dephosphorization were determined by studying the thermodynamic and dynamic conditions of dephosphorization. Through the process of molten iron dephosphorization,100 t converter dephosphorization, ladle dephosphorization, slagging, secondary LF refining and anti-return P process, combined with low P alloy, stable production of ultra-low P welding wire EF3 is realized. By controlling molten iron w[Si]≤0.15% and making high basicity slag with R = 6, it can remove P and S at the same time, achieve molten iron w [P]≤ 0.020%, iron w [S] ≤0.005%; The end temperature of converter is from 1 595 ℃ to 1 610 ℃, the basicity of the final slag is about 4.0, the content of FeO in the final slag is 23.0%-26.0% , the tapping w[P] of the converter is less than 0.008% ;The molten steel w[P] is less than 0.004% by ladle dephosphorization; After dephosphorization with slag removal process, slag removal before and after the basic does not return P, Secondary LF is used to prevent P increase . P increase is very little with low P alloy .The slag removal process is adopted, the P content of molten steel w[P]≤0.005% in tundish can be achieved

Key words: Ultra-low P Welding Wire EF3, Converter, Dephosphorization, Slag, P Content

摘要: 为实现高级别管线用超低P焊丝EF3的批量稳定生产,对脱P的热力学条件和动力学条件研究,明确脱P的条件。通过铁水脱P、100 t转炉脱P、钢包脱P配合扒渣、二次LF精炼防回P工艺,配合低P合金,实现了超低P焊丝EF3的稳定生产。控制铁水w[Si]≤0.15%,造高碱度(R=6)的炉渣,可同时脱P、脱S,实现铁水w[P]≤0.020%、铁水w[S]≤0.005%;转炉终点温度在1 595~1 610 ℃,终渣碱度4.0左右,终渣中w[FeO]在23.0%~26.0%,可实现转炉出钢w[P]≤0.008%;采用钢包脱P,可实现钢水w[P]≤0.004%;钢包脱磷后配合扒渣工艺,扒渣前后基本不回P,采用二次LF精炼防增P,配合低P合金,增P量极少;从而可实现中间包钢水w[P]≤0.005%。

关键词: 超低P焊丝EF3, 转炉, 脱P, 扒渣, P含量

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